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===Ferromagnetism===
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==Tensor==
In ''physics'' a '''tensor''' in its simplest form is a proportionality factor between two [[vector]] quantities that may differ in both magnitude and direction, and which is a relation that remains the same under changes in the coordinate system. Mathematically this relationship in some particular coordinate system is:


{{Image|Hysteresis loops.PNG|right|200px|Add image caption here.Magnetic flux density vs. magnetic field in steel and iron; the curve depends upon the direction of traversal, the phenomenon of [[hysteresis]]}}  
:<math> v_j = \sum_{k} \chi_{jk} w_k \ , </math>
For ferromagnetic materials, the self-interaction of the atoms tends to align them even when no external magnetic field is present. As a result, ferromagnetic materials create a net magnetic field (and magnetic flux density) in the space surrounding the material, and can form permanent magnets at temperatures below the [[Curie temperature]] of the material. At higher temperatures, the aligning interaction is inadequate to overcome the randomness introduced by thermal motions, and the material becomes paramagnetic.


The basis for cooperation between atomic magnetic moments is that electrons obey the [[Pauli exclusion principle]] that no two can occupy the same quantum state. That means configurations with aligned spins are energetically favored over misaligned spins by an ''exchange interaction'', favoring magnetization. The same idea underlies [[Hund's rules]] for atoms, namely, other things equal, electrons in atoms populate states to maximize their total spin. Of course, an unanswered question is why ferromagnetic materials profit from this effect more than other materials.<ref name=exchange>
or, introducing unit vectors '''ê<sub>j</sub>''' along the coordinate axes:


:<math>
\begin{align}
\mathbf {v} & = v_1 \mathbf{\hat {e}_1} + v_2 \mathbf{\hat{e}_2} + ...\\
& = \left(\chi_{11} w_1 +\chi_{12}w_2 ...\right)\mathbf{\hat {e}_1} +\left(\chi_{21} w_1 +\chi_{22}w_2 ... \right)\mathbf{\hat {e}_2} ...
\end{align}


For more about the exchange interaction, see {{cite book |title=Electrodynamics of continuous media |chapter=Chapter V: Ferromagnetism |pages=pp. 146 ''ff'' |author=LD Landau and EM Lifshitz |publisher=Pergamon Press |url=http://books.google.com/books?id=sxAJAQAAIAAJ&dq=editions%3AsxAJAQAAIAAJ&q=take+into+account+only+the+exchange+interaction#search_anchor |year=1960 |LCCN=60-14731}}, and for some simple examples {{cite book |title=Interacting electrons and quantum magnetism |author=Assa Auerbach |chapter=Chapter 2: Spin exchange |url=http://books.google.com/books?id=tiQlKzJa6GEC&pg=PA11 |pages=pp. 11 ''ff'' |isbn=0387942866 |year=1999 |publisher=Springer}}.</ref>


The figure shows ''magnetization curves'' for two different ferromagnetic materials. The curves exhibit ''hysteresis'', that is, the curve is history dependent and, in particular, depends upon the direction in which the magnetic field increases. This complex behavior indicates that magnetization in such materials is not an equilibrium process, and larger samples break up into ''magnetic domains'' or sub-regions of different magnetization directions separated by ''domain walls''.<ref name=Mayergoyz>
</math>


{{cite book |title=The Science of Hysteresis, volume III |editor=Isaak D. Mayergoyz, Giorgio Bertotti, editors |author=F Fiorillo, C Appino and M Pasquale |chapter=§1.3 Energy in a magnetic system. Domain walls and domain structures |isbn=0123694337 |year=2005 |pages=pp. 29 ''ff'' |publisher=Elsevier Academic Press |url=http://books.google.com/books?id=88W3fMqNkRwC&pg=RA2-PA29&dq=%22process+is+an+out-of-equilibrium%22&hl=en&ei=yt8ITd3hM5SssAO51MneDg&sa=X&oi=book_result&ct=result&resnum=1&ved=0CCUQ6AEwAA#v=onepage&q=%22process%20is%20an%20out-of-equilibrium%22&f=false}}
where '''v''' is a vector with components {v<sub>j</sub>} and '''w''' is another vector with components {w<sub>j</sub>} and the quantity <math>\overleftrightarrow\boldsymbol{ \Chi}</math> = {χ<sub>ij</sub>} is a tensor. Because '''v''' and '''w''' are vectors, they are physical quantities independent of the coordinate axes chosen to find their components. Likewise, if this relation between vectors constitutes a physical relationship, then the above connection between '''v''' and '''w''' expresses some physical fact that transcends the particular coordinate system where <math>\overleftrightarrow\boldsymbol{ \Chi}</math> = {χ<sub>ij</sub>}.


</ref> The magnetization curve is affected (in part) by the change in size of the various domains as they adapt to changes in the external field.<ref name= Klüber0>
A rotation of the coordinate axes will alter the components of '''v''' and '''w'''. Suppose the rotation labeled ''A'' is described by the equation:
:<math> \mathbf {\hat {e}'_i} = \Sigma_j A_{ij} \mathbf {\hat {e}_j} \ , </math>  


Same reference as previously, but p. 169:{{cite book |author=J Kübler |title=Theory of itinerant electron magnetism |publisher= Oxford |isbn=0199559023 |year=2009 |edition=Revised ed |url=http://books.google.com/books?id=ZbM0gHCcmaQC&pg=PA169 |chapter=§4.1.1 Stoner theory |pages =pp. 169 ''ff''}}
:<math>\mathbf {\hat {e}_i} = \Sigma_j A^{-1}_{ij} \mathbf {\hat {e}'_j} \ , </math>


</ref>
Then:


Today it is still impossible to predict from first principles that iron is ferromagnetic.<ref name=Graham>
:<math>\mathbf v = \sum_i v_i \mathbf {\hat {e}_i} = \sum_j v'_j \mathbf {\hat {e}'_j} \ , </math>
and
:<math>\mathbf v = \sum_i v_i \sum_j A^{-1}_{ij}  \mathbf {\hat {e}'_j} = \sum_i \sum_k \chi_{ik} w_k \sum_j A^{-1}_{ij}  \mathbf {\hat {e}'_j} \ , </math>


{{cite book |title=Introduction to magnetic materials |author=Bernard Dennis Cullity, Chad D. Graham |url=http://books.google.com/books?id=kk1el8vB4HoC&pg=PA131 |pages=p. 131 |isbn=0471477419 |year=2009 |publisher=Wiley-IEEE |edition=2nd ed |chapter=Chapter 4: Ferromagnetism}}
:<math>\mathbf w = \sum_m w'_m \sum_k A_{mk}  \mathbf {\hat {e}_k} \ ,</math>


</ref> However, some guidance can be obtained as to which metals are candidates, and which are not, based upon estimates of how exchange energy varies with atomic radii and spacing. "The theory of magnetism in solids is one of the central challenges in condensed matter physics, intrinsically involving many-body correlations, long range order and phase transitions..."<ref name=Martin>
:<math>\mathbf v = \sum_i \sum_k \chi_{ik} \sum_m w'_m  A_{mk}  \sum_j A^{-1}_{ij}  \mathbf {\hat {e}'_j} = \sum_m \chi'_{jm} w'_m \mathbf {\hat {e}'_j} \ , </math>


{{cite book |title=Electronic structure: basic theory and practical methods |author=Richard M Martin |publisher=Cambridge University Press |pages=p. 24 |year=2004 |isbn=0521782856}}
so, to be a tensor, the components of <math>\overleftrightarrow\boldsymbol{ \Chi}</math>  transform as:
:<math>\chi'_{jm}= \sum_i \sum_k \chi_{ik}  A_{mk} A^{-1}_{ij} </math>


</ref>
More directly:
:<math> \mathbf v' =  A \mathbf v =  A \overleftrightarrow\boldsymbol{ \Chi} \mathbf w = A  \overleftrightarrow{\boldsymbol {\Chi}}  A^{-1}  A \mathbf w =  A  \overleftrightarrow{\boldsymbol {\Chi}}  A^{-1} \mathbf w' \ ,</math>


where '''v'''' = '''v''' because '''v''' is a vector representing some physical quantity, say the velocity of a particle. Likewise, '''w'''' = '''w'''. The new equation represents the same relationship provided:


<references/>
:<math>\overleftrightarrow\boldsymbol{ \Chi}  = A  \overleftrightarrow {\boldsymbol {\Chi}}A^{-1} \ .</math>
 
 
 
This example is a ''second rank'' tensor. The idea is extended to ''third'' rank tensors that relate a vector to a second rank tensor, as when electric polarization is related to stress in a crystal, and to ''fourth'' rank tensors that relate two second rank tensors, and so on.
 
Tensors can relate vectors of different dimensionality, as in the relation:
 
:<math> \begin{pmatrix}
p_1\\
p_2\\
p_3
\end{pmatrix}
=
\begin{pmatrix}
T_{11} & T_{12} &T_{13}&T_{14}&T_{15}\\
T_{21} & T_{22} &T_{23}&T_{24}&T_{25}\\
T_{31} & T_{32} &T_{33}&T_{34}&T_{35}
 
\end{pmatrix}
\
\begin{pmatrix}
q_1\\
q_2\\
q_3\\
q_4\\
q_5
\end{pmatrix} </math>
[http://books.google.com/books?id=gJA2oahuPSMC&printsec=frontcover&dq=tensor&hl=en&ei=orYKTZmeA4y-sQPN5NjBCg&sa=X&oi=book_result&ct=result&resnum=9&ved=0CE8Q6AEwCDgK#v=onepage&q&f=false Young, p 308]
[http://books.google.com/books?id=aWWWyXthnq8C&printsec=frontcover&dq=tensor&hl=en&ei=WsgKTdDEE5P6sAOh46T9Cg&sa=X&oi=book_result&ct=result&resnum=6&ved=0CEUQ6AEwBTgU#v=onepage&q&f=false Akivis p. 55]
[http://books.google.com/books?id=7xRlVTVSNpQC&printsec=frontcover&dq=tensor&hl=en&ei=WsgKTdDEE5P6sAOh46T9Cg&sa=X&oi=book_result&ct=result&resnum=7&ved=0CEwQ6AEwBjgU#v=onepage&q&f=false p1]
[http://books.google.com/books?id=pgCx01lds9UC&printsec=frontcover&dq=tensor&hl=en&ei=WsgKTdDEE5P6sAOh46T9Cg&sa=X&oi=book_result&ct=result&resnum=10&ved=0CF8Q6AEwCTgU#v=onepage&q&f=false p6]
[http://books.google.com/books?id=gWPH3e-xYHMC&pg=PA1&dq=tensor&hl=en&ei=IMoKTbCHH5OssAOiobWSCg&sa=X&oi=book_result&ct=result&resnum=4&ved=0CDYQ6AEwAzge#v=onepage&q&f=false tensor algebra p. 1]
[http://books.google.com/books?id=-4baDJnuH-sC&pg=PA1&dq=tensor&hl=en&ei=IMoKTbCHH5OssAOiobWSCg&sa=X&oi=book_result&ct=result&resnum=7&ved=0CEYQ6AEwBjge#v=onepage&q&f=false intro]
[http://books.google.com/books?id=oTeGXkg0tn0C&printsec=frontcover&dq=tensor&hl=en&ei=_coKTZ-KG4X2tgOAtvzVCg&sa=X&oi=book_result&ct=result&resnum=3&ved=0CDMQ6AEwAjgo#v=onepage&q&f=false p. 427; ch 14]
[http://books.google.com/books?id=KCgZAQAAIAAJ&pg=PA58&dq=tensor&hl=en&ei=tcsKTbSvDIK8sQPkxNnYCg&sa=X&oi=book_result&ct=result&resnum=8&ved=0CFAQ6AEwBzgy#v=onepage&q=tensor&f=false Weyl]
[http://books.google.com/books?id=14fn03iJ2r8C&pg=PA145&dq=tensor&hl=en&ei=IcwKTdu9IY_CsAPyj-GUCg&sa=X&oi=book_result&ct=result&resnum=5&ved=0CD4Q6AEwBDhG#v=onepage&q=tensor&f=false What is a tensor] [http://books.google.com/books?id=LVTYjmcdvPwC&pg=PA10&dq=negative++%22cyclic+order%22&hl=en&ei=zNUlTbbaBY34sAPdtb3_AQ&sa=X&oi=book_result&ct=result&resnum=5&ved=0CDQQ6AEwBA#v=onepage&q=negative%20%20%22cyclic%20order%22&f=false tensor as operator]

Latest revision as of 04:07, 22 November 2023


The account of this former contributor was not re-activated after the server upgrade of March 2022.


Tensor

In physics a tensor in its simplest form is a proportionality factor between two vector quantities that may differ in both magnitude and direction, and which is a relation that remains the same under changes in the coordinate system. Mathematically this relationship in some particular coordinate system is:

or, introducing unit vectors êj along the coordinate axes:

where v is a vector with components {vj} and w is another vector with components {wj} and the quantity = {χij} is a tensor. Because v and w are vectors, they are physical quantities independent of the coordinate axes chosen to find their components. Likewise, if this relation between vectors constitutes a physical relationship, then the above connection between v and w expresses some physical fact that transcends the particular coordinate system where = {χij}.

A rotation of the coordinate axes will alter the components of v and w. Suppose the rotation labeled A is described by the equation:

Then:

and

so, to be a tensor, the components of transform as:

More directly:

where v' = v because v is a vector representing some physical quantity, say the velocity of a particle. Likewise, w' = w. The new equation represents the same relationship provided:


This example is a second rank tensor. The idea is extended to third rank tensors that relate a vector to a second rank tensor, as when electric polarization is related to stress in a crystal, and to fourth rank tensors that relate two second rank tensors, and so on.

Tensors can relate vectors of different dimensionality, as in the relation:

Young, p 308 Akivis p. 55 p1 p6 tensor algebra p. 1 intro p. 427; ch 14 Weyl What is a tensor tensor as operator