Combustion: Difference between revisions

From Citizendium
Jump to navigation Jump to search
imported>David E. Volk
m (subpages)
mNo edit summary
 
(25 intermediate revisions by 2 users not shown)
Line 1: Line 1:
{{subpages}}
{{subpages}}
[[Image:Et baal.jpg|thumb|200px|[[Flame]] resulting from the combustion (burning) of a [[fuel]]]]
[[Image:Combustion flame.jpg|thumb|200px|Flame resulting from the combustion (burning) of a fuel.]]
'''Combustion''' or '''burning''' is a complex sequence of [[exothermic]] chemical reactions between a [[fuel]] and an [[oxidant]] accompanied by the production of [[heat]] or both [[heat]] and [[light]] in the form of either a glow or [[flame]]s.
'''Combustion''' or '''burning''' is a complex sequence of [[exothermic]] [[chemical reaction]]s between a [[fuel]] and an [[Oxidation|oxidant]] accompanied by the production of [[heat]] or both [[heat]] and [[light]] in the form of either a glow or [[flame]]s. The most commonly used fuels are solid [[coal]] and [[hydrocarbon]] [[gas]]es or [[liquid]]s.


Direct combustion by atmospheric oxygen is a reaction mediated by [[Radical (chemistry)|radical]] intermediates. The conditions for radical production are naturally produced by [[thermal runaway]], where the heat generated by combustion is necessary to maintain the high temperature necessary for radical production.
In complete combustion, a compound such as [[methane]] (CH<sub>4</sub>) reacts with an [[Oxidation|oxidizing]] element such as [[oxygen]] (O<sub>2</sub>) and the combustion products are compounds of each element in the fuel with the oxidizing element. For example:
<center>'''methane + oxygen → carbon dioxide + water vapor'''<br/>
'''CH<sub>4</sub> + 2O<sub>2</sub> → CO<sub>2</sub> + 2H<sub>2</sub>O'''</center>


In a complete combustion reaction, a compound reacts with an oxidizing element, such as [[oxygen]] or [[fluorine]], and the products are compounds of each element in the fuel with the oxidizing element. For example:
A simpler example is the combustion of [[hydrogen]] (H<sub>2</sub>) and oxygen, which is a commonly used reaction in [[rocket]] engines:
 
<center>'''hydrogen + oxygen → water vapor'''<br/>
:{{chem|CH|4}} + 2{{chem|O|2}} → {{chem|CO|2}} + 2{{chem|H|2|O}}
'''2H<sub>2</sub> + O<sub>2</sub> → 2H<sub>2</sub>O'''</center>
:{{chem|CH|2|S}} + 6{{chem|F|2}} → {{chem|CF|4}} + 2{{chem|HF}} + {{chem|SF|6}}
 
In the large majority of the real world uses of combustion, the oxygen oxidant is obtained from the ambient [[air]]. Taking air to contain 79 volume percent of non-combustible [[nitrogen]] (N<sub>2</sub>) and 21 volume percent oxygen, the resultant [[flue gas]] from the combustion of a fuel will contain nitrogen plus the products of combustion:
A simpler example can be seen in the combustion of [[hydrogen]] and [[oxygen]], which is a commonly used reaction in rocket engines:
<center>'''methane + oxygen + nitrogen → carbon dioxide + water vapor + nitrogen'''<br/>
 
'''CH<sub>4</sub> + 2O<sub>2</sub> + 7.52N<sub>2</sub> → CO<sub>2</sub> + 2H<sub>2</sub>O + 7.52N<sub>2</sub>'''</center>
:2{{chem|H|2}} + {{chem|O|2}} → 2{{chem|H|2|O}} + heat
The result is simply water vapor.
 
In the large majority of the real world uses of combustion, the oxygen (O<sub>2</sub>) oxidant is obtained from the ambient air and the resultant [[flue gas]] from the combustion will contain [[nitrogen]]:
 
:{{chem|CH|4}} + 2{{chem|O|2}} + 7.52{{chem|N|2}} → {{chem|CO|2}} + 2{{chem|H|2|O}} + 7.52{{chem|N|2}} + heat


As can be seen, when air is the source of the oxygen, nitrogen is by far the largest part of the resultant flue gas.
As can be seen, when air is the source of the oxygen, nitrogen is by far the largest part of the resultant flue gas.


In reality, combustion processes are never perfect or complete. In flue gases from combustion of [[carbon]] (as in [[coal]] combustion) or carbon [[compound]]s (as in combustion of [[hydrocarbons]], [[wood]] etc.) both unburned carbon (as [[soot]]) and carbon compounds ([[carbon monoxide|CO]] and others) will be present. Also, when air is the oxidant, some nitrogen will be oxidized to various [[nitrogen oxides]] (NO<sub>x</sub>).  
In reality, combustion processes are never perfect or complete. In the flue gases from the combustion of [[carbon]] (as in [[coal]] combustion) or carbon [[compound]]s (as in combustion of [[hydrocarbons]], [[wood]], etc.) both unburned carbon (as [[soot]]) and carbon compounds other than carbon dioxide such as [[carbon monoxide]] (CO) and others will be present. Also, when air is the oxidant, some nitrogen will be oxidized to various [[nitrogen oxides]] (NO<sub>x</sub>).  


==Types==
==Types of combustion==


===Rapid===  
===Rapid===  
Rapid combustion is a form of combustion in which large amounts of heat and [[light]] energy are released, which often results in a [[fire]]. This is used in a form of machinery such as [[internal combustion engine]]s and in [[thermobaric weapon]]s. Sometimes, a large volume of gas is liberated in combustion besides the production of heat and light.The sudden evolution of large quantities of gas creates excessive pressure that produces a loud noise.Such a combustion is known as an [[explosion]].
Rapid combustion is a form of combustion in which large amounts of heat and [[light]] energy are released, which often results in a [[fire]]. This is used in [[internal combustion engine]]s and in [[thermobaric weapon]]s. Sometimes, a large volume of gas is liberated in combustion besides the production of heat and light. The sudden evolution of large quantities of gas creates excessive [[pressure]] that produces a loud noise. Such a combustion is known as an [[explosion]] or [[detonation]].


===Slow===
===Slow===


Slow combustion is a form of combustion which takes place at low temperatures. [[Cellular respiration]] is an example of slow combustion.
Slow combustion is a form of combustion which takes place at low [[temperature]]s. [[Cellular respiration]] is an example of slow combustion.
 
===Complete===
In complete combustion, the reactant will burn in oxygen, producing a limited number of products. When a [[hydrocarbon]] burns in oxygen, the reaction will only yield carbon dioxide and water. When a hydrocarbon or any fuel burns in air, the combustion products will also include nitrogen. When elements such as carbon, nitrogen, sulfur, and iron are burned, they will yield the most common oxides. Carbon will yield carbon dioxide. Nitrogen will yield [[nitrogen dioxide]]. Sulfur will yield [[sulfur dioxide]]. Iron will yield [[iron(III) oxide]]. It should be noted that complete combustion is almost impossible to achieve.  In reality, as actual combustion reactions come to [[Chemical equilibrium|equilibrium]], a wide variety of major and minor species will be present.  For example, the combustion of methane in air will yield, in addition to the major products of carbon dioxide and water, the minor product carbon monoxide and nitrogen oxides, which are products of a side reaction (oxidation of nitrogen).


===Turbulent===
===Turbulent===


Turbulent combustion is a combustion characterized by turbulent flows. It is the most used for industrial application (e.g. gas turbines, diesel engines, etc.) because the turbulence helps the mixing process between the fuel and oxidizer.
Turbulent combustion is a combustion characterized by turbulent flows. It is used for industrial applications such as [[gas turbine]]s and [[diesel engine]]s because the turbulence helps to mix the fuel and oxidizer.


===Microgravity===
===Microgravity===


Nearly every [[Flame]] behaves differently in the [[Microgravity environment]]. Microgravity  combustion research contributes to understanding of spacecraft fire safety and diverse aspects of combustion physics.
Nearly every flame behaves differently in a [[Microgravity| microgravity environment]]. Microgravity  combustion research contributes to understanding of [[spacecraft]] fire safety and diverse aspects of combustion physics.


===Incomplete===
===Incomplete===


Incomplete combustion occurs when there isn't enough oxygen to allow the fuel (usually a hydrocarbon) to react completely with the oxygen to produce carbon dioxide and water, also when the combustion is quenched by a heat sink such as a solid surface or flame trap. When a hydrocarbon burns in air, the reaction will yield [[carbon dioxide]], water, [[carbon monoxide]], pure carbon (soot or ash) and various other compounds such as [[nitrogen oxides]].
Incomplete combustion occurs when there isn't enough oxygen to allow the fuel (usually a hydrocarbon) to react completely with the oxygen to produce carbon dioxide and water or when the combustion is quenched by a heat sink such as a solid surface or a flame trap.  


The quality of combustion can be improved by design of combustion devices, such as [[burner]]s and [[internal combustion engines]]. Further improvements are achievable by [[catalytic]] after-burning devices (such as [[catalytic converter]]s) or by the simple partial return of the exhaust gases into the combustion process. Such devices are required by [[environmental legislation]] for cars in most countries, and may be necessary in large combustion devices, such as [[thermal power plants]], to reach legal [[emission standards]].
The quality of combustion can be improved by the design of combustion devices such as furnace [[burner]]s and [[internal combustion engine]]s. Further improvements are achievable by [[catalytic]] after-burning devices or by the simple partial return of the exhaust gases into the combustion process. Such devices are required by [[environmental legislation]] for vehicles in most countries, and may be necessary in large combustion sources, such as the [[Steam generator|steam generating furnaces]] in [[thermal power plants]], to reach legal [[emission standard]]s.


{{Image|Smouldering.jpg|right|175px|Smouldering embers of a solid barbecue fuel.}}
===Smouldering===
===Smouldering===
[[Smouldering]] is a flameless form of combustion. The fundamental difference between smouldering and flaming combustion is that in smouldering, the oxidation occurs on the surface of a solid fuel rather than in the gas phase. The characteristic [[temperature]] and [[heat]] released during smouldering are low compared to those in flaming combustion (i.e., ~ 600°C vs. ~&thinsp;1500°C). Smouldering propagates in a creeping fashion, around 0.1 mm/s, which is about ten times slower than flames spread over a solid. In spite of its weak combustion characteristics, smouldering is a significant fire hazard.


[[Smoulder|Smouldering combustion]] is a flameless form of combustion, deriving its heat from heterogeneous reactions occurring on the surface of a solid fuel when heated in an '''oxidizing''' environment. The fundamental difference between smouldering and flaming combustion is that in smouldering, the oxidation of the reactant species occurs on the surface of the solid rather than in the gas phase. The characteristic temperature and heat released during smouldering are low compared to those in the flaming combustion of a solid. Typical values in smouldering are around 600 °C for the peak temperature and 5 kJ/g-O<sub>2</sub> for the heat released; typical values during flaming are around 1500 °C and 13 kJ/g-O<sub>2</sub> respectively. These characteristics cause smoulder to propagate at low velocities, typically around 0.1 mm/s, which is about two orders of magnitude lower than the velocity of flame spread over a solid. In spite of its weak combustion characteristics, smouldering is a significant fire hazard.
==Combustion with other oxidants==


==Combustion with other oxidants==
Oxygen is usually assumed as the oxidant when talking about combustion, but other oxidants exist. [[Nitrous oxide]] (NO) is used in rockets and in race cars. [[Fluorine]] (F<sub>2</sub>), another oxidizing element, can produce a combustion reaction that yields fluorinated products rather than oxides. For example, mixtures of gaseous fluorine and methane are explosive. [[Chlorine trifluoride]] is a strong fluorinating agent that ignites fuels more readily than oxygen.
[[Oxygen]] can be assumed as the oxidant when talking about combustion, but other oxidants exist. [[Nitrous oxide]] is used in rockets and in motorsport; it produces oxygen at over 1300 C. Fluorine, another oxidizing element, can produce a combustion reaction, to produce fluorinated products (rather than oxides). For example, mixtures of gaseous [[fluorine]] and [[methane]] are explosive, just like mixtures of oxygen and methane. [[Chlorine trifluoride]] is a strong fluorinating agent that ignites fuels more readily than oxygen.


==Chemical equation==
==Chemical equations==


Generally, the [[chemical equation]] for [[Stoichiometry|stoichiometric]] burning of [[hydrocarbon]] in oxygen is as follows:
Generally, the [[chemical equation]] for [[Stoichiometry|stoichiometric]] burning of hydrocarbon in oxygen is as follows:
:<math>C_xH_y + \left( x + \frac{y}{4} \right) O_2 \rightarrow \; xCO_2 + \left( \frac{y}{2} \right) H_2O</math>
:'''C<sub>x</sub>H<sub>y</sub> + (&thinsp;x + 0.25 y&thinsp;)&thinsp;O<sub>2</sub> → x&thinsp;CO<sub>2</sub> + (&thinsp;0.50 y&thinsp;)&thinsp;H<sub>2</sub>O'''


For example, the burning of [[propane]] is:
For example, the burning of [[propane]] is:
:<math>C_3H_8 + 5O_2 \rightarrow \; 3CO_2 + 4H_2O</math>
:'''C<sub>3</sub>H<sub>8</sub> + 5&thinsp;O<sub>2</sub> → 3&thinsp;CO<sub>2</sub> + 4&thinsp;H<sub>2</sub>O


The simple word equation for the combustion of a hydrocarbon in oxygen is:
The simple word equation for the combustion of a hydrocarbon in oxygen is:
:<math>\textrm{Fuel} + \textrm{Oxygen} \rightarrow \; \textrm{Heat} + \textrm{Water} + \textrm{Carbon\ dioxide}</math>
:'''fuel + oxygen → carbon dioxide + water vapor


If the combustion takes place using air as the oxygen source, the nitrogen can be added to the equation, although it does not react, to show the composition of the flue gas:
If the combustion takes place using air as the oxygen source, the nitrogen can be added to the equation, although it does not react, to show the composition of the flue gas:
:<math>C_xH_y + \left( x+ \frac{y}{4} \right) O_2 + 3.76 \left( x+ \frac{y}{4} \right) N_2 \rightarrow \; xCO_2 + \left( \frac{y}{2} \right) H_2O + 3.76 \left( x + \frac{y}{4} \right) N_2</math>
:'''C<sub>x</sub>H<sub>y</sub> + (&thinsp;x + 0.25&thinsp;y&thinsp;)&thinsp;O<sub>2</sub> + 3.76&thinsp;(&thinsp;x + 0.25&thinsp;y&thinsp;)&thinsp;N<sub>2</sub> → x&thinsp;CO<sub>2</sub> + (&thinsp;0.50&thinsp;y&thinsp;)&thinsp;H<sub>2</sub>O + 3.76&thinsp;(&thinsp;x + 0.25&thinsp;y&thinsp;)&thinsp;N<sub>2</sub>'''


For example, the burning of [[propane]] is:
For example, the burning of propane in air is:
:<math>C_3H_8 + 5O_2 + 18.8N_2 \rightarrow \; 3CO_2 + 4H_2O + 18.8N_2</math>
:'''C<sub>3</sub>H<sub>8</sub> + 5&thinsp;O<sub>2</sub> + 18.8&thinsp;N<sub>2</sub> → 3&thinsp;CO<sub>2</sub> + 4&thinsp;H<sub>2</sub>O + 18.8&thinsp;N<sub>2</sub>
 
The simple word equation for the combustion of a hydrocarbon in air is:


The simple word equation for the combustion of a hydrocarbon in air  is:
:'''fuel + air → carbon dioxide + water + nitrogen
:<math>\textrm{Fuel} + \textrm{Air} \rightarrow \; \textrm{Heat} + \textrm{Water} + \textrm{Carbon\ dioxide} + \textrm{Nitrogen}</math>


Nitrogen may also oxidize when there is an excess of oxygen. The reaction is thermodynamically favored only at high temperatures. [[Diesel engines]] are run with an excess of oxygen to combust small particles that tend to form with only a stoichiometric amount of oxygen, necessarily producing nitrogen oxide emissions. Both the United States and European Union are planning to impose limits to nitrogen oxide emissions, which necessitate the use of a special [[catalytic converter]] or treatment of the exhaust with [[urea]].
Nitrogen may also oxidize when there is an excess of oxygen. The reaction is thermodynamically favored only at high temperatures. Diesel engines are run with an excess of oxygen to combust small particles that tend to form with only a stoichiometric amount of oxygen, necessarily producing nitrogen oxide emissions.


==Fuels==
==Fuels==
===Liquid fuels===
===Liquid fuels===


Combustion of a liquid fuel in an oxidizing atmosphere actually happens in the gas phase. It is the vapour that burns, not the liquid. Therefore, a liquid will normally catch fire only above a certain temperature, its [[flash point]]. The flash point of a liquid fuel is the lowest temperature at which it can form an ignitable mix with air. It is also the minimum temperature at which there is enough evaporated fuel in the air to start combustion.
Combustion of a liquid fuel in an oxidizing atmosphere actually happens in the gas phase. It is the vapour that burns, not the liquid. Therefore, a liquid will normally catch fire only above a certain temperature, its [[Flash point (science)|flash point]]. The flash point of a liquid fuel is the lowest temperature at which it can form an ignitable mix with air. It is also the minimum temperature at which there is enough evaporated fuel in the air to start combustion.


===Solid fuels===
===Solid fuels===


The act of combustion consists of three relatively distinct but overlapping phases:
The act of combustion consists of three relatively distinct but overlapping phases:
* '''Preheating phase''', when the unburned [[fuel]] is heated up to its flash point and then [[fire point]]. Flammable gases start being evolved in a process similar to [[dry distillation]].
* '''Preheating phase''', when the unburned fuel is heated up to its flash point and then [[fire point]]. Flammable gases start being evolved in a process similar to [[dry distillation]].
* '''Distillation phase''' or '''gaseous phase''', when the mix of evolved flammable gases with oxygen is ignited. Energy is produced in the form of heat and light.  [[Flames]] are often visible. Heat transfer from the combustion to the solid maintains the evolution of flammable vapours.  
* '''Distillation phase''' or '''gaseous phase''', when the mix of evolved flammable gases with oxygen is ignited. Energy is produced in the form of heat and light.  Flames are often visible. Heat transfer from the combustion to the solid maintains the evolution of flammable vapors.  
* '''Charcoal phase''' or '''solid phase''', when the output of flammable gases from the material is too low for persistent presence of flame and the [[charring|charred]] fuel does not burn rapidly anymore but just glows and later only [[smoulder]]s.
* '''Charcoal phase''' or '''solid phase''', when the output of flammable gases from the material is too low for persistent presence of flame and the charred fuel does not burn rapidly anymore but just glows and later only smoulders.
 
==Reaction mechanism==
Combustion in oxygen is a radical chain reaction where many distinct radical intermediates participate.
 
The high energy required for initiation is explained by the unusual structure of the dioxygen molecule. The lowest-energy configuration of the dioxygen molecule is a stable, relatively unreactive diradical in a [[triplet oxygen|triplet spin state]]. Bonding can be described with three bonding electron pairs and two antibonding electrons, whose [[Spin (physics)|spin]]s are aligned, such that the molecule has nonzero total angular momentum. Most fuels, on the other hand, are in a singlet state, with paired spins and zero total angular momentum. Interaction between the two is quantum mechanically a "[[forbidden transition]]", i.e. possible with a very low probability. To initiate combustion, energy is required to force dioxygen into a spin-paired state, or [[singlet oxygen]]. This intermediate is extremely reactive. The energy is supplied as heat. The reaction produces heat, which keeps it going.
 
Combustion of hydrocarbons is thought to be initiated by the abstraction of a hydride radical (H) from the fuel to oxygen, to give a hydroperoxide radical (HOO). This reacts further to give hydroperoxides, which break up to give [[hydroxyl]] radicals. There are a great variety of these processes that produce fuel radicals and oxidizing radicals. Oxidizing species include singlet oxygen, hydroperoxide, hydroxyl, monatomic oxygen, and hydroperoxyl (OH<sub>2</sub>). Such intermediates are short-lived and cannot be isolated. However, non-radical intermediates are stable and are produced in incomplete combustion. An example is [[acetaldehyde]] produced in the combustion of [[ethanol]]. An intermediate in the combustion of carbon and hydrocarbons, [[carbon monoxide]], is of special importance because it is a [[Poison|poisonous gas]].
 
Solid fuels also undergo a great number of [[pyrolysis]] reactions that give more easily oxidized, gaseous fuels. These reactions are endothermic and require constant energy input from the combustion reactions. A lack of oxygen or other poorly designed conditions result in these noxious and carcinogenic pyrolysis products being emitted as thick, black smoke.
 
==Temperature==
Assuming perfect combustion conditions, such as complete combustion under [[adiabatic]] conditions (i.e., no heat loss or gain), the adiabatic combustion temperature can be determined. The formula that yields this temperature is based on the [[first law of thermodynamics]] and takes note of the fact that the [[heat of combustion]] is used entirely for heating the fuel, the combustion air or oxygen, and the combustion product gases (commonly referred to as the ''[[flue gas]]'').
 
In the case of fossil fuels burnt in air, the combustion temperature depends on
* the [[Heat of combustion|heating value]]
* the [[air-fuel ratio|stoichiometric air to fuel ratio]] <math>{\lambda}</math>
* the [[specific heat capacity]] of fuel and air
* the air and fuel inlet temperatures
 
The adiabatic combustion temperature (also known as the ''[[adiabatic flame temperature]]'') increases for higher heating values and inlet air and fuel temperatures and for stoichiometric air ratios approaching one.
 
Most commonly, the adiabatic combustion temperatures for coals are around 2200 °C (for inlet air and fuel at ambient temperatures and for <math>\lambda = 1.0</math>), around 2150 °C for oil and 2000 °C for natural gas.
 
In industrial [[furnace|fired heaters]], [[power plant]] steam generators, and large [[gas turbine|gas-fired turbines]], the more common way of expressing the usage of more than the stoichiometric combustion air is [[air-fuel ratio|''percent excess combustion air'']].  For example, excess combustion air of 15 percent means that 15 percent more than the required stoichiometric air is being used.
 
==Instabilities==
 
Combustion instabilities are typically violent pressure oscillations in a combustion chamber.  These pressure oscillations can be as high as 180dB, and long term exposure to these cyclic pressure and thermal loads reduces the life of engine components.  In rockets, such as the F1 used in the Saturn V program, instabilities led to massive damage of the combustion chamber and surrounding components. This problem was solved by re-designing the fuel injector.  In liquid jet engines the droplet size and distribution can be used to attenuate the instabilities.  Combustion instabilities are a major concern in ground-based gas turbine engines because of NOx emissions. The tendency is to run lean, an equivalence ratio less than 1, to reduce the combustion temperature and thus reduce the NOx emissions; however, running the combustor lean makes it very susceptible to combustion instabilities.
 
The [[Rayleigh Criterion]] is the basis for analysis of thermoacoustic combustion instabilities and is evaluated using the Rayleigh Index over one cycle of instability.{{Fact|date=October 2007}}
 
:<math>G(x)=\frac{1}{T}\int_{T}q'(x,t)p'(x,t)dt</math>
 
When the heat release oscillations are in phase with the pressure oscillations the Rayleigh Index is positive and the magnitude of the thermoacoustic instability increases.  Consecutively if the Rayleigh Index is negative then thermoacoustic damping occurs.  The Rayleigh Criterion implies that a thermoacoustic instability can be optimally controlled by having heat release oscillations 180 degrees out of phase with pressure oscillations at the same frequency.  This minimizes the Rayleigh Index.{{Fact|date=October 2007}}


==See also==
{| border="0" width="215" align="right" cellpadding="0" cellspacing="0" style="wrap=no"
|
{| class = "wikitable" align="right"
|+ Adiabatic Flame Temperatures
!Gas!!Formula!!°C
|-
|Hydrogen||H<sub>2</sub>||2,181
|-
|Methane||CH<sub>4</sub>||2,014
|-
|Ethane||C<sub>2</sub>H<sub>6</sub>||2,063
|-
|Ethylene||C<sub>2</sub>H<sub>4</sub>||2,231
|-
|Propane||C<sub>3</sub>H<sub>8</sub>||2,076
|-
|Propylene||C<sub>3</sub>H<sub>6</sub>||2,171
|-
|Butane||C<sub>4</sub>H<sub>10</sub>||2,078
|-
|Pentane||C<sub>5</sub>H<sub>12</sub>||2,083
|-
|Hexane||C<sub>6</sub>H<sub>14</sub>||2,087
|-
|colspan=3|<span style="font-size:0.85em;">Notes:<br/>Gas temperature = 25 °C<br/>Combustion air temperature = 25 °C<br/>Air relative humidity = 60%<br/>Excess combustion air = 0 %</span>
|}
|}
==Adiabatic flame temperature==
Assuming complete combustion under [[adiabatic]] conditions (i.e., no heat loss or gain), the ''adiabatic flame temperature'' can be calculated. The calculation is based on the [[Laws of thermodynamics|first law of thermodynamics]] (i.e., the ''conservation of energy'') and on the fact that the [[heat of combustion]] is used entirely for heating the fuel, the combustion air or oxygen, and the combustion product gases.<ref name>{{cite book|author=Milton R.Beychok|title=[[Fundamentals of Stack Gas Dispersion]]|edition=4th Edition|publisher=author-published|year=2005|pages=pp. 173-177|id=ISBN 0-9644588-0-2}}</ref><ref>[http://myweb.ncku.edu.tw/~chuhsin/ppt/combustion%20principles%20and%20control/04-Flame%20Temperature.ppt Flame Temperature] Professor Hsin Chu, [[National Cheng Kung University]], [[Taiwan]]</ref>


{{col-begin}} {{col-break}}
In the case of fossil fuels burnt in air, the combustion temperature depends on:
==== Related concepts ====
* the heat of combustion (also referred to as the ''heating value'')
* [[Air-fuel ratio]]
* the stoichiometric [[air-fuel ratio]] <math>{\lambda}</math>
* [[Deflagration]]
* the [[Specific heat|specific heat capacity]] of the fuel and the air
* [[Detonation]]
* the air and fuel inlet temperatures, as well as the relative humidity of the air
* [[Fire]]
* [[Flue gas emissions from fossil fuel combustion]]
* [[Flue gas stacks]]
* [[Gas stoichiometry]]
* [[Heat of combustion]]
* [[Phlogiston theory]] (historical)
* [[Pyrolysis]]
* [[Pyrophoric]]
* [[Smouldering]]
* [[Spontaneous combustion]]
* [[Stoichiometry]]
* [[Chemical looping combustion]]
{{col-break}}


==== Machines and equipment ====
The adiabatic flame temperature increases for higher heating values and for higher inlet air and fuel temperatures and for stoichiometric air-fuel ratios approaching one.
* [[Boiler]]
* [[Water heater]]
* [[Cyclone furnace]]
* [[External combustion engine]]
* [[Furnace#industrial furnaces|Industrial furnaces]]
* [[Gas turbine]]
* [[Internal combustion engine]]
* [[Jet engine]]
* [[Rocket engine]]
* [[Rotary combustion engine]]
* [[Staged combustion cycle (rocket)]]


{{col-break}}
Most commonly, the approximate adiabatic flame temperatures for coals are 2200 °C, 2150 °C for [[fuel oil]]s and 2000 °C for [[natural gas]]es. The adjacent table lists some calculated adiabatic flame temperatures for hydrogen and for various hydrocarbon gases, all at the conditions stated in the notes at the bottom of the table.
==== Measurement techniques ====
* [[Calorimeter]]
* [[Coherent anti-Stokes Raman spectroscopy]] (CARS)
* [[Laser Doppler velocimetry]]
* [[Laser-induced fluorescence]]
* [[Particle image velocimetry]]
* [[Thin filament pyrometry]]


==== Social applications and issues ====
In industrial [[furnace|fired heaters]], [[power plant]] steam generators, and large [[gas turbine|gas-fired turbines]], the more common way of expressing the usage of more than the stoichiometric combustion air is ''percent excess combustion air''.  For example, excess combustion air of 15 percent means that 15 percent more than the required stoichiometric air is being used.
* [[Global warming]]
* [[Immolation]]
{{col-end}}


==External links==
==References==
*[http://www25.brinkster.com/denshade/hydro.html Hydrocarbon combustion] Simple applet that illustrates the Chemical equation.
{{reflist}}
*[http://www.normanchigier.com/Fuel_Injection_email.html Fuel efficiency (stoichiometric air fuel mixture) vs. decreased emissions in combustion engines]
'''General:'''<br/>
*[http://www.habmigern2003.info Combustion Analysis] The principles of exhaust fume analysis for assessing combustion quality in boilers.
*{{cite book|author=Merle C. Potter and Craig W. Somerton|title=Schaum's Outline of Thermodynamics for Engineers|edition=2nd Edition|publisher=McGraw-Hill|year=2006|id=ISBN 0-07-146306-2}}<br/>
* [http://mark.jelezniak.de/Chemked/index.htm Simulation of gas combustion]
*{{cite book|author=Steven S. Zumdahl|title=Introductory Chemistry: A Foundation|edition=5th Edition|publisher=Brooks Cole|year=2003|id=ISBN 0-618-30499-1}}<br/>
*{{cite book|author=Warren C. Strahle|title=An Introduction to Combustion|edition=1st Edition|Publisher=CRC Press|year=1993 |id=ISBN 2-88124-608-7}}[[Category:Suggestion Bot Tag]]

Latest revision as of 16:01, 30 July 2024

This article is developing and not approved.
 Main Article
 Discussion
Related Articles  [?]
Bibliography  [?]
External Links  [?]
Citable Version  [?]
 
https://en.citizendium.org/wiki/index.php?title=Combustion&printable=yes
This editable Main Article is under development and subject to a disclaimer.
Flame resulting from the combustion (burning) of a fuel.

Combustion or burning is a complex sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat or both heat and light in the form of either a glow or flames. The most commonly used fuels are solid coal and hydrocarbon gases or liquids.

In complete combustion, a compound such as methane (CH4) reacts with an oxidizing element such as oxygen (O2) and the combustion products are compounds of each element in the fuel with the oxidizing element. For example:

methane + oxygen → carbon dioxide + water vapor
CH4 + 2O2 → CO2 + 2H2O

A simpler example is the combustion of hydrogen (H2) and oxygen, which is a commonly used reaction in rocket engines:

hydrogen + oxygen → water vapor
2H2 + O2 → 2H2O

In the large majority of the real world uses of combustion, the oxygen oxidant is obtained from the ambient air. Taking air to contain 79 volume percent of non-combustible nitrogen (N2) and 21 volume percent oxygen, the resultant flue gas from the combustion of a fuel will contain nitrogen plus the products of combustion:

methane + oxygen + nitrogen → carbon dioxide + water vapor + nitrogen
CH4 + 2O2 + 7.52N2 → CO2 + 2H2O + 7.52N2

As can be seen, when air is the source of the oxygen, nitrogen is by far the largest part of the resultant flue gas.

In reality, combustion processes are never perfect or complete. In the flue gases from the combustion of carbon (as in coal combustion) or carbon compounds (as in combustion of hydrocarbons, wood, etc.) both unburned carbon (as soot) and carbon compounds other than carbon dioxide such as carbon monoxide (CO) and others will be present. Also, when air is the oxidant, some nitrogen will be oxidized to various nitrogen oxides (NOx).

Types of combustion

Rapid

Rapid combustion is a form of combustion in which large amounts of heat and light energy are released, which often results in a fire. This is used in internal combustion engines and in thermobaric weapons. Sometimes, a large volume of gas is liberated in combustion besides the production of heat and light. The sudden evolution of large quantities of gas creates excessive pressure that produces a loud noise. Such a combustion is known as an explosion or detonation.

Slow

Slow combustion is a form of combustion which takes place at low temperatures. Cellular respiration is an example of slow combustion.

Turbulent

Turbulent combustion is a combustion characterized by turbulent flows. It is used for industrial applications such as gas turbines and diesel engines because the turbulence helps to mix the fuel and oxidizer.

Microgravity

Nearly every flame behaves differently in a microgravity environment. Microgravity combustion research contributes to understanding of spacecraft fire safety and diverse aspects of combustion physics.

Incomplete

Incomplete combustion occurs when there isn't enough oxygen to allow the fuel (usually a hydrocarbon) to react completely with the oxygen to produce carbon dioxide and water or when the combustion is quenched by a heat sink such as a solid surface or a flame trap.

The quality of combustion can be improved by the design of combustion devices such as furnace burners and internal combustion engines. Further improvements are achievable by catalytic after-burning devices or by the simple partial return of the exhaust gases into the combustion process. Such devices are required by environmental legislation for vehicles in most countries, and may be necessary in large combustion sources, such as the steam generating furnaces in thermal power plants, to reach legal emission standards.

(PD) Photo: Jens Buurgaard Nielsen
Smouldering embers of a solid barbecue fuel.

Smouldering

Smouldering is a flameless form of combustion. The fundamental difference between smouldering and flaming combustion is that in smouldering, the oxidation occurs on the surface of a solid fuel rather than in the gas phase. The characteristic temperature and heat released during smouldering are low compared to those in flaming combustion (i.e., ~ 600°C vs. ~ 1500°C). Smouldering propagates in a creeping fashion, around 0.1 mm/s, which is about ten times slower than flames spread over a solid. In spite of its weak combustion characteristics, smouldering is a significant fire hazard.

Combustion with other oxidants

Oxygen is usually assumed as the oxidant when talking about combustion, but other oxidants exist. Nitrous oxide (NO) is used in rockets and in race cars. Fluorine (F2), another oxidizing element, can produce a combustion reaction that yields fluorinated products rather than oxides. For example, mixtures of gaseous fluorine and methane are explosive. Chlorine trifluoride is a strong fluorinating agent that ignites fuels more readily than oxygen.

Chemical equations

Generally, the chemical equation for stoichiometric burning of hydrocarbon in oxygen is as follows:

CxHy + ( x + 0.25 y ) O2 → x CO2 + ( 0.50 y ) H2O

For example, the burning of propane is:

C3H8 + 5 O2 → 3 CO2 + 4 H2O

The simple word equation for the combustion of a hydrocarbon in oxygen is:

fuel + oxygen → carbon dioxide + water vapor

If the combustion takes place using air as the oxygen source, the nitrogen can be added to the equation, although it does not react, to show the composition of the flue gas:

CxHy + ( x + 0.25 y ) O2 + 3.76 ( x + 0.25 y ) N2 → x CO2 + ( 0.50 y ) H2O + 3.76 ( x + 0.25 y ) N2

For example, the burning of propane in air is:

C3H8 + 5 O2 + 18.8 N2 → 3 CO2 + 4 H2O + 18.8 N2

The simple word equation for the combustion of a hydrocarbon in air is:

fuel + air → carbon dioxide + water + nitrogen

Nitrogen may also oxidize when there is an excess of oxygen. The reaction is thermodynamically favored only at high temperatures. Diesel engines are run with an excess of oxygen to combust small particles that tend to form with only a stoichiometric amount of oxygen, necessarily producing nitrogen oxide emissions.

Fuels

Liquid fuels

Combustion of a liquid fuel in an oxidizing atmosphere actually happens in the gas phase. It is the vapour that burns, not the liquid. Therefore, a liquid will normally catch fire only above a certain temperature, its flash point. The flash point of a liquid fuel is the lowest temperature at which it can form an ignitable mix with air. It is also the minimum temperature at which there is enough evaporated fuel in the air to start combustion.

Solid fuels

The act of combustion consists of three relatively distinct but overlapping phases:

  • Preheating phase, when the unburned fuel is heated up to its flash point and then fire point. Flammable gases start being evolved in a process similar to dry distillation.
  • Distillation phase or gaseous phase, when the mix of evolved flammable gases with oxygen is ignited. Energy is produced in the form of heat and light. Flames are often visible. Heat transfer from the combustion to the solid maintains the evolution of flammable vapors.
  • Charcoal phase or solid phase, when the output of flammable gases from the material is too low for persistent presence of flame and the charred fuel does not burn rapidly anymore but just glows and later only smoulders.
Adiabatic Flame Temperatures
Gas Formula °C
Hydrogen H2 2,181
Methane CH4 2,014
Ethane C2H6 2,063
Ethylene C2H4 2,231
Propane C3H8 2,076
Propylene C3H6 2,171
Butane C4H10 2,078
Pentane C5H12 2,083
Hexane C6H14 2,087
Notes:
Gas temperature = 25 °C
Combustion air temperature = 25 °C
Air relative humidity = 60%
Excess combustion air = 0 %

Adiabatic flame temperature

Assuming complete combustion under adiabatic conditions (i.e., no heat loss or gain), the adiabatic flame temperature can be calculated. The calculation is based on the first law of thermodynamics (i.e., the conservation of energy) and on the fact that the heat of combustion is used entirely for heating the fuel, the combustion air or oxygen, and the combustion product gases.[1][2]

In the case of fossil fuels burnt in air, the combustion temperature depends on:

  • the heat of combustion (also referred to as the heating value)
  • the stoichiometric air-fuel ratio
  • the specific heat capacity of the fuel and the air
  • the air and fuel inlet temperatures, as well as the relative humidity of the air

The adiabatic flame temperature increases for higher heating values and for higher inlet air and fuel temperatures and for stoichiometric air-fuel ratios approaching one.

Most commonly, the approximate adiabatic flame temperatures for coals are 2200 °C, 2150 °C for fuel oils and 2000 °C for natural gases. The adjacent table lists some calculated adiabatic flame temperatures for hydrogen and for various hydrocarbon gases, all at the conditions stated in the notes at the bottom of the table.

In industrial fired heaters, power plant steam generators, and large gas-fired turbines, the more common way of expressing the usage of more than the stoichiometric combustion air is percent excess combustion air. For example, excess combustion air of 15 percent means that 15 percent more than the required stoichiometric air is being used.

References

  1. ↑ Milton R.Beychok (2005). Fundamentals of Stack Gas Dispersion, 4th Edition. author-published, pp. 173-177. ISBN 0-9644588-0-2. 
  2. ↑ Flame Temperature Professor Hsin Chu, National Cheng Kung University, Taiwan

General:

  • Merle C. Potter and Craig W. Somerton (2006). Schaum's Outline of Thermodynamics for Engineers, 2nd Edition. McGraw-Hill. ISBN 0-07-146306-2. 
  • Steven S. Zumdahl (2003). Introductory Chemistry: A Foundation, 5th Edition. Brooks Cole. ISBN 0-618-30499-1. 
  • Warren C. Strahle (1993). An Introduction to Combustion, 1st Edition. ISBN 2-88124-608-7. 
Retrieved from "https://citizendium.org/wiki/index.php?title=Combustion&oldid=967835"