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| == '''[[Volatility (chemistry)]]''' ==
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| ''by [[User:Anthony.Sebastian|Anthony.Sebastian]] and [[User:Milton Beychok|Milton Beychok]]
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| | | ==Footnotes== |
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| {{Image|Vapor Pressure Chart2.png|right|250px|Example vapor pressure graphs of various liquids.}} | |
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| In [[chemistry]] and [[physics]], '''volatility''' is a term used to characterize the tendency of a substance to vaporize.<ref>'''Note:''' To vaporize means to become a [[vapor]], the gaseous state of the substance.</ref> It is directly related to a substance' s [[vapor pressure]]. At a given [[temperature]], a substance with a higher vapor pressure will vaporize more readily than a substance with a lower vapor pressure.<ref>[http://www.bae.uky.edu/~snokes/BAE549thermo/gasesvapor.htm Gases and Vapor] ([[University of Kentucky]] website)</ref><ref>{{cite book|author=James G. Speight|title=The Chemistry and Technology of Petroleum|edition=4th Edition|publisher=CRC Press|date=2006|isbn=0-8493-9067-2}}</ref><ref name=Kister>{{cite book|author=Kister, Henry Z.|title=[[Distillation Design]]|edition=1st Edition|publisher=McGraw-Hill|year=1992|isbn=0-07-034909-6}}</ref> In other words, at a given temperature, the more volatile the substance the higher will be the pressure of the vapor in dynamic equilibrium with its vaporizing substance—i.e., when the rates at which molecules escape from and return into the vaporizing substance are equal.
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| In common usage, the term applies primarily to [[liquid]]s. However, it may also be used to characterize the process of [[Sublimation (chemistry)|sublimation]] by which certain [[solid]] substances such as [[ammonium chloride]] (NH<sub>4</sub>Cl) and [[dry ice]], which is solid [[carbon dioxide]] (CO<sub>2</sub>), change directly from their solid form to a vapor without becoming a liquid.
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| Any substance with a significant vapor pressure at temperatures of about 20 to 25 °[[Celsius (unit)|C]] (68 to 77 °[[Fahrenheit (unit)|F]]) is very often referred to as being ''volatile''.
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| === Vapor pressure, temperature and boiling point ===
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| The vapor pressure of a substance is the pressure at which its gaseous (vapor) phase is in equilibrium with its liquid or solid phase. It is a measure of the tendency of [[molecule]]s and [[atom]]s to escape from a liquid or solid.
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| At [[atmospheric pressure]]s, when a liquid's vapor pressure increases with increasing temperatures to the point at which it equals the atmospheric pressure, the liquid has reached its [[boiling point]], namely, the temperature at which the liquid changes its state from a liquid to a gas throughout its bulk. That temperature is very commonly referred to as the liquid's ''normal boiling point''.
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| Not surprisingly, a liquid's normal boiling point will be at a lower temperature the greater is the tendency of its molecules to escape from the liquid, namely, the higher is its vapor pressure. In other words, the higher is the vapor pressure of a liquid, the higher is the volatility and the lower is the normal boiling point of the liquid. The adjacent vapor pressure chart graphs the dependency of vapor pressure upon temperature for a variety of liquids<ref name=Perry>{{cite book|author=R.H. Perry and D.W. Green (Editors)|title=Perry's Chemical Engineers' Handbook | edition=7th Edition|publisher=McGraw-Hill|year=1997|id=ISBN 0-07-049842-5}}</ref> and also confirms that liquids with higher vapor pressures have lower normal boiling points.
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| ''[[Volatility (chemistry)|.... (read more)]]''
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| ! style="text-align: center;" | [[Volatility (chemistry)#References|notes]]
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| {{reflist|2}} | | {{reflist|2}} |
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Latest revision as of 09:19, 11 September 2020
The Mathare Valley slum near Nairobi, Kenya, in 2009.
Poverty is deprivation based on lack of material resources. The concept is value-based and political. Hence its definition, causes and remedies (and the possibility of remedies) are highly contentious.[1] The word poverty may also be used figuratively to indicate a lack, instead of material goods or money, of any kind of quality, as in a poverty of imagination.
Definitions
Primary and secondary poverty
The use of the terms primary and secondary poverty dates back to Seebohm Rowntree, who conducted the second British survey to calculate the extent of poverty. This was carried out in York and was published in 1899. He defined primary poverty as having insufficient income to “obtain the minimum necessaries for the maintenance of merely physical efficiency”. In secondary poverty, the income “would be sufficient for the maintenance of merely physical efficiency were it not that some portion of it is absorbed by some other expenditure.” Even with these rigorous criteria he found that 9.9% of the population was in primary poverty and a further 17.9% in secondary.[2]
Absolute and comparative poverty
More recent definitions tend to use the terms absolute and comparative poverty. Absolute is in line with Rowntree's primary poverty, but comparative poverty is usually expressed in terms of ability to play a part in the society in which a person lives. Comparative poverty will thus vary from one country to another.[3] The difficulty of definition is illustrated by the fact that a recession can actually reduce "poverty".
Causes of poverty
The causes of poverty most often considered are:
- Character defects
- An established “culture of poverty”, with low expectations handed down from one generation to another
- Unemployment
- Irregular employment, and/or low pay
- Position in the life cycle (see below) and household size
- Disability
- Structural inequality, both within countries and between countries. (R H Tawney: “What thoughtful rich people call the problem of poverty, thoughtful poor people call with equal justice a problem of riches”)[4]
As noted above, most of these, or the extent to which they can be, or should be changed, are matters of heated controversy.
- ↑ Alcock, P. Understanding poverty. Macmillan. 1997. ch 1.
- ↑ Harris, B. The origins of the British welfare state. Palgrave Macmillan. 2004. Also, Oxford Dictionary of National Biography.
- ↑ Alcock, Pt II
- ↑ Alcock, Preface to 1st edition and pt III.
