Count Rumford

PD Image
Colonel Benjamin Thompson, FRS. Painting by Thomas Gainsborough 1783

Count Rumford (born Benjamin Thompson, 1753–1814) was an American born soldier, statesman, scientist, inventor and social reformer, who is most famous for his scientific work. During his time in the military, his work with cannons led him to discover that friction can generate an inexhaustible amount of heat, which challenged the caloric theory that regarded heat as a substance.

Thompson's other career achievements include attaining the rank of colonel in the British army, being elected a Fellow of the Royal Society in England in 1779, being knighted by King George III in 1781, and being ennobled to Count of the Holy Roman Empire by the Duke of Bavaria in 1792.

Biography

Early life

Benjamin Thompson was born on March 26, 1753 in Woburn, Massachusetts. His father was a farmer who died when Benjamin was twenty months old. He attended grade school in Woburn, where he demonstrated an aptitude for mathematics. At age thirteen, he left school and was apprenticed as a shop assistant. Thompson recognized early on that this was not a career he wished to pursue and sought to further his education on this own. In his spare time he studied chemistry, physics, and anatomy under the tutelage of community elders. He demonstrated a particular interest in science and technology, attempting to replicate Benjamin Franklin's kite and key experiment, make fireworks, and build a perpetual motion machine. When he turned eighteen he decided to try his hand at teaching and was invited to run a school in Concord. It was there that he met Sarah Walker, a wealthy window who was eleven years his senior, and married her in November 1772. His wife introduced him to the ruling circles of New England where he made such an impression that at the age of twenty he received a major's commission in the second New Hampshire Regiment, even though he had no military experience whatsoever.

American Revolutionary War

During the American war of Independence (1775-1783) Thompson was a loyalist, choosing to remain loyal to the British. This made him unpopular in New Hampshire and he fled to Boston, where he offered his services to General Thomas Gage and served as a spy on the Continental Army. Thompson proved to be skilled at his craft, transmitting letters using invisible ink. When Boston was taken by the Americans on March 17, 1776 Thompson fled to England leaving his wife and daughter behind. He would never see his wife again, but his daughter Sarah would join him in Europe twenty years later.

Upon his arrival in England, he presented himself to Lord George Germain, the Secretary of State for the Colonies in the cabinet of Lord North, bearing letters of recommendation from New Hampshire Governor John Wentworth and General William Howe. The meeting resulted in a lifelong friendship. Thompson provided Germain with accurate information about the war and in return Germain gave Thompson an entry into English society. Germain's influence with King George III procured Thompson an appointment as Secretary of the Province of Georgia, which although a meaningless sinecure, brought him £100 per annum. This position left him enough time to perform an important series of scientific experiments on the properties of gunpowder. He investigated whether humid—water containing—gunpowder was more forceful than dry powder, as was often thought. He adapted a very clever experimental setup, based on ideas first put forth by Benjamin Robins in New Principles of Gunnery in 1742 and improved upon by mathematician Charles Hutton in 1778, with both the gun and its heavy wooden target as free-swinging pendulums, so that he could measure accurately the forces of recoil and impact. He found that the vaporization of water did not improve the quality of gunpowder, or in other words, dry gunpowder works better. The scientific worth of this research was recognized and Thompson was made a Fellow of the Royal Society at the age of twenty-seven. A year later he published his findings in a 99-page paper entitled New Experiments upon Gunpowder, in the 1781 volume of the Philosophical Transactions of the Royal Society.

Thompson climbed rapidly in English society and in 1779 he was appointed deputy to the Inspector General of Provincial Forces. Thompson's sole responsibility was to provide clothing and other stores for the British colonial armed forces. The position turned out to be very lucrative, enabling him to take advantage of the fact that silk, widely used in uniforms, is hygroscopic; dry silk bought in London would absorb 10 percent of its weight in the journey across the Atlantic, which allowed him to make a considerable profit. It was reported that Thompson made about £7000 per year, which led to accusations of corruption. However, these charges appear to have been ignored and in 1780 he was promoted to Under Secretary of State for the Colonies.

With the war in America going poorly, as well as his friendship with the unpopular Lord Germain, made Thompson's political career uncertain. Using the wealth he had recently accumulated, he bought himself an appointment as lieutenant-colonel of the King's American dragoons. Abandoning his post as Under Secretary, he left England and arrived in Charleston December 29, 1781. From there, he traveled to New York where he started to enlist men for his regiment and by August 1782 the King's American Dragoons were ready for service. The Dragoons were involved in several skirmishes, however, soon after (on November 30, 1782) the hostilities ceased and the Treaty of Paris was signed on September 3, 1783.

Bavarian years

The end of the war left Thompson with an uncertain future. Although Britain was at peace, he decided his interests lied in continuing his military career and central Europe seemed to offer him the best chances. In an attempt to enhance his image he used his contacts in London to receive a promotion to full colonel, had his portrait painted in full military regalia, and obtained a letter of recommendation from Lord North. On his way to Vienna, Thompson stopped in Strasbourg where Prince Maximilian von Zweibrücken of Bavariawas reviewing his troops. The two men became lifelong friends, which was an amazing feat given the class consciousness and the importance attached to noble birth in eighteenth century Europe. Through Maximilian's influence Thompson became colonel in the Bavarian army and aide-de-camp to the Prince-Elector (German: Kurfürst) of Bavaria, Karl II (Karl Philipp Theodor, 1724 – 1799), as well as tutor to his illegitimate son.

Before Thompson could accept this position, he had to return to England to ask for permission as he was still a servant of King George III. The English government saw his appointment as an excellent chance to gain influence in Bavaria (an independent state in the Holy Roman Empire), and not only granted him permission but also knighted him. Thompson would stay in Bavaria for twelve years climbing through the ranks. Thompson's first four years spent absorbing the culture of Bavaria and learning to speak German and French. He observed a country that was disorganized, full of corruption, and ripe for reform. On February 7, 1788 he submitted a plan to the Elector outlining his plans for reorganizing the military. The plan was well received and Thompson was promoted to rank of major-general and given the the positions of Minister of War, Minister of Police, and Chamberlain to the Court.

Prior to Thompson's reforms, the Bavarian army was in disarray, with about a quarter of the men being officers. Although Bavaria is completely landlocked and had no navy, it did have a great admiral. The common soldiers were mainly conscripted, unwilling, underpaid, and untrained peasants. Full of energy Thompson tackled these problems. Some of his sweeping reforms included increasing the pay of the soldiers and setting up schools to educate them, establishing a military academy for the training of officers, softening disciplinary procedures, eliminating army service as a criminal punishment, and introducing scientific principles in nutrition, so that the men were fed well (and at less cost). He also reorganized the manufacturing of cannon.

Thompson's next round of reforms were targeted at the impoverished population. It was estimated that about five percent of Bavarians lived on begging. Gangs of beggars were highly territorial and operated in a Mafia-like manner. Thompson's plan was to round them all up and employ them in workhouses making military uniforms. On New Year's Day 1790, the military arrested all the beggars they could find in Munich. This plan worked to a large extent since Thompson took care that the regime in the workhouses was benign and inmates were trained in a wide variety of skills and paid on a piecework basis. The social experiment was a success and many beggars were reabsorbed into society.

Another great success of Thompson's, inspired by the Kew Gardens in London, was the construction of the English Garden on a patch of marshy ground on the banks of the Isar River. The Garden, which was the finest park in Europe when it opened to the public in 1791, still exists in the city of Munich today.

Although Thompson did not have the best relationship with the people of Bavaria, his successful reform programs solidified his popularity with the Elector. On May 9,1792 Karl II promoted him to a the rank and dignity of the Imperial Counts of the Holy Roman Empire. Sir Benjamin Thompson, Fellow of the Royal Society, chose the title Count Rumford, after the New Hampshire town which he had left behind sixteen years ago.

Politically, the situation was shifting in the wrong direction for Count Rumford at the end of 1792. During his energetic enterprises he had made many enemies in Munich and, moreover, his protector, Karl Theodor (Karl II), was aging and losing power. In March 1793, the Count, with his health declining, found it opportune to be out of sight for a while and was granted permission to travel to Italy where he spent the next sixteen months. When Rumford returned to Bavaria in the summer of 1794, the political situation was worsening. While in Italy, Rumford had met Alessandro Volta and Charles Bladgen,the secretary of the Royal Society, who inspired him to spend more time on science. The Elector granted the Count six months leave of absence to pursue his scientific endeavors, which Rumford decided to spend in London.

Back in England

Back in England Count Rumford wrote several essays about his work in Munich on bettering the conditions of the poor. New work was his article on the improvement of the construction of chimneys. He used his understanding of convection to design a better fireplace, with a shelf at the back of the chimney so that cold air falling down the chimney struck this shelf and was deflected to join the hot air rising from the fire. This prevented clouds of smoke entering the room. In London Rumford was appreciated as a scientist and a statesman and he stretched his leave to almost a year. When his daughter Sally (Sarah) joined him in March 1796, the Count felt so benevolent to mankind that he endowed two prize medals with his own money. One was to the Royal Society in London and the other to the American Academy of Arts and Sciences in Boston. They are still awarded by both institutions today.

In August 1796 Count Rumford could not postpone his return to Munich any longer because the city was in great danger. It was caught in the middle between opposing French and Austrian armies and the powers ruling Munich thought that a foreigner would be a convenient scapegoat if the town were invaded. So Rumford became Town Commandant. The Austrians set up camp on the North side of town and the French to the west. Each army was determined to occupy Munich, but Rumford, shuttling between the camps and playing for time, managed to avoid triggering any conflict until the French were pulled out following the defeat of another French army. Rumford, who had defended Munich without a drop of blood being shed, was honored by a monument in the English garden and his daughter was made Countess. When the danger was over, Rumford found time to do his famous cannon boring experiments that established the thermodynamic connection between heat and work. However, Rumford's impopularity with the ruling classes grew with the day, and it seemed better all around that Rumford would return to England. As a face-saving resolution the Elector appointed Count Rumford to Minister Plenipotentiary to the Court of St James (Bavarian Ambassador in London), where Rumford arrived 19 September 1798.

Back in London he found that King George III did not accept his credentials because as a British national he could not serve a foreign government. The King's decision turned out well for science, because Rumford found the time to establish a combined museum, research and educational institute, which was granted the Royal Seal in Januari 1800 to become the Royal Institution of Great Britain. The first professor of the Royal Institution, Thomas Garnett, was soon replaced by Humphry Davy, who was to make the institution a huge success in promoting the public understanding of the natural sciences.

Last years in Paris

Soon after appointing Davy, Rumford visited Munich to pay his respects to the successor of Elector Karl Theodor (Karl II). The new Elector was his old friend Maximilian von Zweibrücken, who took the name Maximilian IV. (Shortly before the end of the Holy Roman Empire in 1806 he became King Maximilian I of Bavaria). On his way back to England Rumford stopped over in Paris where he made the acquaintance of the widow of the great chemist Lavoisier who was decapitated during the Reign of Terror. They started an affair and in 1804 the couple settled in a house in Paris. In October 1805, after Rumford received proof that his American wife was deceased, the couple married. Although they had had an affair for almost five years, they soon found that they were incompatible and separated after a couple of years. Rumford found a house in Auteuil about four miles from the center of Paris where he lived from 1808 until his death on 21 August 1814 at the age of sixty-one.

Part of table from English translation of Ref.

Rumford's science

As has been mentioned above, Thompson's research on the explosive power of gunpowder obtained him a membership of the Royal Society. In the second half of the 1780s, while he was restructuring the Bavarian army, Colonel Thompson's interest in army uniforms led him to the study of the conduction of heat. He discovered that convection of air is an important carrier of heat, but that still air is a good insulator. The Royal Society awarded him the Copley medal for this work. Thompson was the kind of scientist who loved to apply his findings to practical applications. In this case it lead him to the design of fluffy woollen army uniforms for the winter and cotton uniforms for the summer.

At the end of the eighteenth century there were two competing theories of heat (flow of energy from hot to cold). Antoine Lavoisier held that heat is a fluid and is better called caloric, just as dephlogisticated air is better called oxygen; see the reproduction of part of Lavoisier's book on the left. Another theory—the now generally accepted kinetic theory—held that heat is a form of motion of the particles constituting matter. The particles of a hot body move more vehemently than the ones of a cold body. Count Rumford adhered to the latter theory. If heat/caloric were a fluid of which a finite amount would be contained in matter, it would be possible to exhaust it, in the same way as burning a log of wood gives off a finite amount of heat—ashes are deplete of caloric.

Rumford demonstrated in Munich around 1797, shortly after he saved the city from plunder by either the French or the Austrian army, that the heat generated by friction is inexhaustible. To show this, he bored a brass cylinder, waste product of the Munich cannon foundry, with a blunt drill bit. The setup was such that the cylinder was rotated by two horses who did their work via a system of gears, while the drill bit was stationairy. The friction generated an enormous amount of heat which Rumford was able to measure quantitatively by heating water. The conclusion was that heat was inexhaustible: as long as the horses kept working and the drill bit was boring the cylinder, heat continued being generated. Rumford could quickly bring large quantities of water to boil without any fire, to the great astonishment of visitors whom he showed the experiment. But Rumford liked to point out that this is not the most efficient way to heat water, more efficient would be, he said, the burning of the hay that fed the horses. With this remark he was on the edge of understanding that energy is conserved (first law of thermodynamics) and that energy can be converted from one form to another. It took about fifty more years before this principle was understood by men such as Julius Mayer and James Joule.

Work is a form of energy. For instance, the work necessary to lift a kilogram from the surface of the Earth to a height of one meter is 9.81 joule (see Acceleration due to gravity). Energy used to have also a definition in terms of heat: one kilocalorie (kcal) of energy can heat a liter water from 14.5 to 15.5 ⁰C. Rumford was the first to see the equivalence of work and heat and was able to express an amount of heat in a corresponding amount of work. From his cannon-boring experiments he determined that 1 cal = 5.60 joule

A further blow to the caloric theory was when Rumford determined that heat is weightless (the physicist says massless). This can be expected if heat is a motion of constituting particles; if it is a fluid it can be expected to have some weight. Rumford filled three identical bottles with equal weights of water, mercury and alcohol, all of temperature 16 ⁰C. Since on cooling down the three substances give off widely varying amounts of heat (the compounds have very different heat capacity), it could be expected that after cooling down to −1 ⁰C, the bottles have different weight. Such a "null experiment" can be executed with great accuracy, and this is what Rumford did, finding no weight difference whatsoever.

Rumford presented his findings in a communication entitled Enquiry Concerning the Source of Heat Which Is Excited by Friction, to the Royal Society in 1798. Since then the idea that heat is a form of motion is generally accepted, although some of Rumford's contemporaries such as Laplace and John Dalton died unconvinced of the kinetic theory.

Rumford was also an inventor in the field of lighting, heating and cooking. He developed (around 1806) an oil lamp that gave six times more light than the existing Argand lamp, although the latter lamp, invented in 1780, was already a great improvement on the candle light in use before that. In order to make sure that developments on his lamps were really improvements, Rumford invented a photometer by which the yields of lamps could be assessed objectively.

(CC) Photo: Ben Sheldon
The Rumford fireplace, which is still used today.

The Rumford fireplace was briefly mentioned above. Further improvements were in the shape of the chimney and the fireplace itself. The Rumford fireplace radiated more heat for less fuel than the old fireplaces. The Rumford fireplace was a great success and is still on the market—mainly for the purpose of restoring old houses into their original state.

Another great success was his invention of an embryonic kitchen range, not unlike those used today, together with what came to be called a Rumford roaster. In the kitchen range up to twelve separate fireplaces could be built in and they were designed to heat special pots, pans, kettles, etc. all invented by Rumford. The Rumford roaster was designed for cooking meat that hitherto had been done on a spit over an open fire. Rumford also revolutionized cooking for armies in the field.