Magnetically equivalent

From Citizendium
Revision as of 08:14, 8 October 2008 by imported>Sekhar Talluri (add subpages tag)
Jump to navigation Jump to search
This article is developing and not approved.
Main Article
Discussion
Related Articles  [?]
Bibliography  [?]
External Links  [?]
Citable Version  [?]
 
This editable Main Article is under development and subject to a disclaimer.

If a set of nuclei exist in identical environments, they are expected to have the same chemical shift. Such nuclei are called chemically equivalent. If in addition, each member of the set has exactly same interaction (J-coupling) to every other magnetically active nucleus in the molecule, then the nuclei are also magnetically equivalent. A set of nuclei that are magnetically equivalent will also be chemically equivalent, however, chemical equivalence does not guarantee magnetic equivalence. e.g. all protons in benzene are magnetically equivalent.