Ether (disambiguation)
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Ether (chemistry): A chemical compound in which two hydrocarbons are joined together by an intervening oxygen atom; denoted R-O-R. In the past, diethyl ether was used as an anesthetic; still widely used in industrial chemistry [e]
An ether is a chemical compound in which two hydrocarbons are joined together by an intervening oxygen atom. Ethers, particularly diethyl ether, often called simply ether, and tetrahydrofuran (THF) are common solvents for organic chemistry reactions. Diethyl ether was one of the first anaesthetic agents. Many ethers are extremely flammable, and thus use of diethyl ether in the operating room, in the presence of high oxygen levels, in no longer used. Synthesis of ethersThe Williamson synthesis of ethers uses the nucleophilic nature of alkoxide ions to react with primary alkyl halides using an SN2 reaction mechanism. Thus, the reaction of sodium isoproproxide reacts with n-butyl iodide to produce the asymmetric ether n-butyl isopropyl ether. Primary alkyl halides are used to minimize the E2 reaction mechanism. In a method analoguos to the hydration of alkenes, ethers can be formed by reacting alkenes with an alcohol and an acid catalyst, or with an alcohol and mecury acetate. The Williamson synthesis, but not alkene-based methodes, can also be used to from cyclic ethers like tetrahydrofuran. To produce cyclic ethers, a primary alkane is used that contains a halide atom at one end and an alcohol on the other end to undergo an intramolecular reaction. The addtion of the strong base sodium hydroxide (NaOH) creates an alkoxide ion from the alcohol. The alkoxide end reacts with the halogenated carbon in an SN2 mechanism, cyclizing the compound while eliminating the halogen atom. Thus, 4-chloro-1-butanol, in the presence of sodium hydroxide, produces tetrahydrofuran. Oxiranes, also called epoxides are class of cyclic ethers with only two carbon atoms and one oxygen atom in the ring structure. In addition to the Wiliamson ether synthesis (in which case the starting material, which has neighbouring hydroxyl and halide groups, is called a halohydrin), oxiranes may be formed by reacting an alkene with a peroxyacid, a carboxylic acid with the OH group replaced by an OOH group. The most common of these is meta-chloroperbenzioc acid (mCPBA). cleavage reactions of ethersEthers are readily cleaved with the addition of heat and a strong acid such as hydrogen iodide (HI). HI is often used because it is acidic enough to protonate the oxygen atom of an ether and the iodide ion is nucleophilic enough to attack the alkyl group of the protonated ether. Thus, anisole (methyl phenyl ether) can be cleavage to produce phenol and methyl iodide in the presence of HI and heat. Because oxiranes are less stable than other cyclic ethers due to ring strain, hydrogen bromide (HBr) can be used, without additional heat, to cleave oxiranes such as trans-2,3-dimethyl oxirane. The acid-catalyzed ring-opening of the oxirane enantiomer shown here produces (2S,3R)-3-bromo-2-butanol. Oxirane rings can also be broken by the nucleophilic attack of either of the oxirane carbon atoms. Common nucleophiles such as alkoxides and amines can open oxiranes and build up a chemical structure.(Read more...) | ||||||||||||||||||||||||||
Ether (physics): Medium that can carry electromagnetic waves (obsolete) [e]
The ether (also spelled[1] aether) was a concept in physics made obsolete in 1905 by Einstein's theory of special relativity. The idea of an ether was introduced into science by Descartes in Principia philosophiae (1644). Until that time, forces between two bodies that are not in direct contact were assumed to act through space—by action at a distance. Descartes replaced this explanation by one based on an intermediate medium (ether) consisting of vortices that transmit forces between bodies at a distance. The ether concept became especially predominant in the 19th century by the work of Young and Fresnel who revived Huygens' wave theory of light. They replaced Newton's light corpuscles by waves propagating through the ether. In order to explain stellar aberration, first observed in the 1720s and then shown to be caused by the velocity of Earth relative to the velocity of Newton's light corpuscles, Young (1804) assumed ether to be in a state of absolute rest. Maxwell showed in the 1860s that light waves are electromagnetic waves transverse (perpendicular) to the direction of the propagation of the waves. Following Young and Fresnel, Maxwell assumed that electromagnetic waves are vibrations of the ether. In the 19th century it was known that transverse waves are not possible in a gas or a liquid, but only in a solid; hence ether was thought to have solid-like properties. Since light behaves in closed rooms the same as in open fields, and many materials are transparent to light, ether was assumed to fill up all of space and all of matter. Thus, at the end of the 19th century physicists had a picture of the ether as a quasi-rigid solid (not completely rigid because it can vibrate), luminiferous (light carrying) medium that is massless and transparent, at absolute rest, and present everywhere. Today, the concept of ether does not play a role any longer in physics, but in daily life the word lives on in connection with radio and television signals, which commonly are said to be transmitted "through the ether". HistoryIt is not really possible to speak of "the" ether, because as a scientific concept it evolved through three centuries, from Descartes (1596 – 1650), who conceived it as a whirlpool of rotating chains of particles, to Hendrik Antoon Lorentz (1853 – 1928), who saw ether as a transparent massless solid at complete rest. Its only shared property, conserved through the centuries, is that it permeates all space and all matter, even the interstitial spaces between the atoms. Through the centuries ether served three different purposes:
Middle agesThe name ether comes from ancient Greek αἰθήρ (aithèr) where it means the upper, radiating, air. Aristotle introduced it as a fifth element (quinta essentia) next to Earth, Fire, Water, and (sea-level) Air. Aristotelian philosophy was introduced into Western Europe in the 13th century by scholastics as Albertus Magnus (ca. 1200–1280) and Thomas Aquinas (1225–1274). After Aristotelianism was accepted by the Church, Aristotle's views on the nature of motion were incorporated into medieval natural philosophy: a heavy object has as its natural place the center of the universe (which before 1600 was the center of the globe) and a light object has as its natural place the sphere of the Moon. Matter strives for its natural place in the universe, ergo a stone falls down and smoke rises up. DescartesRené Descartes considered the medieval views on motion occult and therefore superseded; he believed instead that all forces are transmitted by direct contact. With regard to the actions between bodies not touching each other, such as two magnets, or the influence of the Moon's position on the tides, he postulated that they must be in direct contact through intermediate contiguous matter. The force is transmitted through this matter—the ether—by two agencies, pressure and impact. Space, in Descartes' view, is a plenum occupied by an ether, which, imperceptible to the senses, is capable of transmitting forces on material bodies immersed in it. Descartes assumed that the ether particles are in constant motion, but, as there is no empty space for them to move to, he inferred that they move to places vacated by other ether particles. The particles participate then in the spinning motions of closed chains of particles (vortices). The Cartesian theory of light is—in the eyes of the modern beholder—rather convoluted. In the first place it is assumed that the speed of light is infinite and yet light is seen as a projectile whose velocity varies from one medium to another. The vehicle of light is "matter of the second kind", which is intermediate between vortex matter and ordinary, ponderable matter. This matter of the "second kind" forms globules and different rotational velocities of the globules give light of different colors. Hooke, Huygens and NewtonThe next event relevant to the history of ether is the publication (1665) of Micrographia by Robert Hooke (1635–1703). Hooke's description of the propagation of light is mechanical and in that sense it resembles that of Descartes. However, while the Cartesian hypothesis is a static pressure in the ether, Hooke's theory concerns a rapid vibrational motion of small amplitude. He introduces the idea of a wave front, which twelve years later (in 1679) was borrowed by Christiaan Huygens (1629–1695), who greatly improved and extended the wave theory of light. Huygens assumed that the ether, the medium in which light propagates, penetrates all matter and is even present in the vacuum. Huygens' ether was, like Descartes', constituted of particles. Huygens interpreted gravitation—a typical action without apparent direct contact—in terms of ether particles that are rapidly rotating in the space surrounding the planet. His rotating particles are reminiscent of the Cartesian vortices, which is not surprising as Descartes had had a strong influence on the young Huygens, whom he had known personally as a child. Hooke's and Huygens' theories were obliterated (at least for over a century) by their contemporary, the scientific giant Isaac Newton (1642–1727). Newton started his career as a strict adherent of ether theory. He wrote in 1672 and 1675: (as summarized in Ref. [2])
Newton suggested three mechanisms by which light may proceed through the ether. His second suggestion that light consists of "multitudes of unimaginable small and swift corpuscles of various sizes springing from shining bodies" was generally selected by later scientists. In 1675 Newton submitted a memorandum to the Royal Society in which, among other things, he explained gravity. He wrote that ether condenses continually in bodies such as Earth and therefore there is a constant downward stream of it that impinges on gross bodies and carries them along. Further Newton suggested in this memorandum that the resulting movement of ether holds the planets in closed orbits.[3] Later, when writing the Principia (1687), Newton become more inclined toward considering gravity as an action at a distance. He realized that this would not be easily digested by his contemporaries, who had just freed themselves of the Aristotelian notion that an object falls downward because of its natural place in the universe. And, indeed, he was right. Huygens and Leibniz were very critical of the idea of attraction at a distance. In the second edition of the Principia (1713), Newton defended his point of view by adding a "General Scholium" in which he attacked the vortex theory of Descartes, pointed out that his gravitational law was mathematically correct, that he did not know the deeper reason for it, and pronounced Hypotheses non fingo (I do not make up hypotheses). Because of Newton's enormous influence on 18th century science, action at a distance was no longer seen as a problem and generally accepted. This is witnessed by the resistance that Michael Faraday met in the early 19th century when he cast doubt on the action-at-a-distance concept for electric and magnetic forces. The 18th century did not see much development in the theory of light, and Newton's corpuscular theory was universally accepted. It was forgotten that he had stated that light particles travel through ether; ether was not important to most 18th century natural philosophers. Young and FresnelEther re-entered the forefront of physics when Thomas Young revived the undulatory (wave) theory of light in 1800.[4]. He noticed that Newton's emission theory: a light source emits corpuscles—had problems with the interference of light and with the simultaneous refraction and reflection of light falling under an angle on the surface of water. Wave theory can account elegantly for both effects, while corpuscular theory cannot. Young's theory was adapted and extended by his 15-year younger French contemporary Augustin-Jean Fresnel. Both workers recognized that stellar aberration needed to be explained by undulatory theory. Stellar aberration was discovered by James Bradley in 1725–1726. A year later (1727) he explained his discovery in the framework of Newton's corpuscular theory. Bradley noted that the velocity of the stellar light observed on Earth, cE, is the resultant of the absolute velocity of light, c, expressed with respect to a frame attached to the fixed stars, minus the velocity of the planet v relative to the same absolute frame. The vectors cE≡ c−v and c make a small angle, the aberration angle. Thus, Bradley transformed the velocity c of the light-corpuscles from an absolute frame fixed to the stars to a frame attached to the moving globe. While doing this, he derived that the aberration angle is proportional to the ratio v/c, a ratio that was to become very important in 19th century physics. The speed of Earth, v, is about 3×104 m/s and c ≈ 3×108 m/s, so that v/c ≈ 10−4. In 1804 Young made a first step in explaining stellar aberration by the wave theory when he assumed that the ether is at absolute rest, that is, ether offers the absolute reference frame used by Bradley. In the absolute frame light propagates with speed c (speed in vacuum). It was known in the early 19th century that light waves travel through a transparent material—such as a block of glass—with a speed, cg, lower than c, while the corpuscular theory had reasons to suppose that cg was larger than c. Thus, the wave theory predicts the index of refraction n of the material[5] to be larger than unity. The refractive properties of a prism depend, through Snell's law, on n and hence on the speed of light cg in the glass. François Arago was of the rather obvious opinion that the speed of light relative to the prism, which is fixed to Earth, should enter Snell's law. Inspired by Bradley's theory of stellar aberration, he performed in 1810 telescopic observations of the speed of stellar light. He mounted a prism on a telescope and observed stars situated at different angles in the sky, exhibiting different aberration angles. According to the Newton-Bradley theory, the light rays from the stars at different angles have different velocities relative to the prism; these should be observable in the refraction patterns of the prism. Arago got a null result, he did not observe any effects. This null effect was the first of several to come in the next hundred years or so. The largest differences in speed of light on Earth can be expected when a fixed star is on the horizon, and the planet travels parallel to its light rays, toward or away from the star. The absolute speed of light (measured by an observer motionless in the ether, the velocities on one line) is, where v is the speed of Earth; v is positive when the planet goes in the same direction as the stellar light and negative if it goes in opposite direction. Note that c=cg +v is a special case of the vector equation c=cE+v, introduced above. In 1818 Fresnel gave some thoughts about incorporating Arago's observations in the wave theory of light. He made the assumption that ether is "dragged" along by the glass of the prism, so that the relative ether-glass speed is reduced. The ether in a transparent body is entrained with velocity v(1-1/n2) when the body itself moves with velocity v with respect to the absolute ether.[6] The "ether drag factor" (1−1/n2) reduces the absolute speed of light, which becomes according to Fresnel, Fresnel showed that inclusion of this drag factor into the theory gives contributions to Arago's results that start with (v/c)2, too small to be observable. In 1851 Armand Hippolyte Louis Fizeau was able to confirm Fresnel's drag factor experimentally by guiding light through flowing water. For a while wave theory had difficulties in explaining birefringence (double refraction) and the associated phenomenon of polarization of light. Around 1820 Fresnel was able to account for these effects by assuming that light in a crystal is a transverse wave (a vibration perpendicular to the propagation direction). In analogy he inferred that light propagating through the ether consists also of transverse waves. This was confirmed in 1861 when Clerk Maxwell showed that (visible) light is just a special kind of electromagnetic waves. Ether in the second half of the 19th centuryMichael Faraday, one of the fathers of electromagnetism, had a strong dislike of hypothetical entities for which no convincing experimental evidence existed. As a consequence, he was skeptical about the existence of the ether. But at the same time he was opposed to electric and magnetic action-at-a-distance theories, which he replaced by field theories. James Clerk Maxwell, who tread in Faraday's footsteps and accepted the physical reality of fields, formulated a mathematical theory of electromagnetic waves that propagate through the luminiferous ether. The difference between Faraday's conception of a field without an ether and Maxwell's conception of a field with an ether is subtle and not easy to understand for a modern physicist. The ether, in the view of Maxwell and almost all physicists at that time, permeates all space and has many of the characteristics of a polarizable dielectric. Further, Maxwell was of the opinion that terrestrial optical experiments aimed at determining Fresnel's ether drag, which is quadratic [i.e., of order (v/c)2], are not sensitive enough to detect the influence of the drag. The Michelson-Morley ExperimentAlbert Abraham Michelson disagreed with Maxwell, judging that it was possible to observe quadratic effects on Earth.[7] While Michelson was on leave in Berlin (1881), he built an interferometer that was sensitive enough to detect effects of the order (v/c)2 and tried to determine the speed v of Earth with respect to the ether. In other words, Michelson aimed to measure the speed of the "ether wind". He compared the times it takes for light to travel the same distance either parallel or transversely to Earth's motion relative to the ether. However, his conclusion was that the speed of the ether wind is zero. H. A. Lorentz found an error in Michelson's theory of the experiment and was dubious about his interpretation of the result. Lord Rayleigh (John William Strutt), who was a strict believer in ether, urged Michelson to repeat the experiment. So, Michelson, who in the meantime was appointed at Case School of Applied Science in Cleveland, Ohio, repeated the experiment in collaboration with Edwin Williams Morley, a chemist from Western Reserve University, also in Cleveland. They built an new interferometer and in August 1887 they measured again a null effect (a speed of 4.7 km/s or less was found, while 30 km/s was expected). [8] Upon being informed of this null result, H. A. Lorentz[9] and George FitzGerald, both adherents of ether, independently postulated that rods fixed to Earth show a dynamic (i.e., due to a change in molecular forces) length contraction, where l′ is the length of the rod when it is oriented parallel to v; its length is l when it is perpendicular to v. When they applied this contraction formula to the arms of the Michelson-Morley interferometer, they could account for the null effect. Later Lorentz showed that the contraction is the first term in a series development of the exact formula,[10] HertzMaxwell's electromagnetic theory was difficult for his contemporaries and hence did not receive much response. This changed in the mid-1880s when Heinrich Rudolf Hertz was able to generate waves of the kind predicted by Maxwell. (Hertz produced electromagnetic waves of wavelengths from a centimeter to a meter, much longer than the wavelengths of visible light that are on the order of 500 nm). As a 19th century physicist, who had studied under Hermann von Helmholtz, Hertz was committed to the ether idea throughout his life. His conviction of the ether’s importance developed throughout his career, intensified during his research on electromagnetic waves, and finally became his chief preoccupation during the final years of his life. After Hertz's empirical confirmation of the existence of Maxwell’s electromagnetic waves, it was universally assumed that the ether, as a carrier of these waves, was proved to exist, too. The experiments of Hertz had an overwhelming impact on physics. They occurred in the formative years of a generation of physicists who dedicated themselves to electromagnetism and who raised the ether to the status of one of the basic building blocks of nature. In a letter to Hertz dated August 14, 1889 from Oliver Heaviside, one of the founding fathers of electromagnetic theory, there is this paragraph:[11]
Decline of the etherAt the end of the 19th century the ether served two purposes: first and foremost it was a transport medium for electromagnetic vibrations. Secondly it offered an absolute frame of reference. With regard to the latter it must be pointed out that in pre-Copernican times, when Earth was seen as the immobile center of the universe, the absolute frame of reference was so naturally fixed to our planet that the question of an absolute frame did not arise. When Copernicus posited that our planet is orbiting the immobile sun, then without much ado the absolute frame was shifted to the sun. But when it was observed that the sun, too, moves with respect to the fixed stars, the existence of a frame at absolute rest became problematic. The ether had solved this problem, or so was the communis opinio around 1890. Of course, there was still the remaining problem of the speed of the Earth and light on Earth with respect to the ether. Around the change of the century physicists started to realize that ether was not indispensable as a transport medium. Hertz had quipped: "Maxwell's theory is Maxwell's system of equations", by which he meant that Maxwell's equations for the propagation of electromagnetic waves are valid irrespective of the model for the underlying ether. Paul Drude wrote in 1900: "The conception of an ether absolutely at rest is the most simple and the most natural—at least if the ether is conceived to be not a substance but merely space endowed with certain physical properties."[12] The death knell of the ether tolled in 1905, when Einstein published his special theory of relativity.[13] [14] Einstein assumed that an absolute reference frame does not exist and, even more than that, he showed that physics is not in need of such a frame. He declared that all inertial frames are equivalent, one cannot prefer one over another (see special relativity). At one stroke he solved the problem of the speed of light, too: this speed is the same in any inertial frame, and is independent of the velocity that a frame may have with respect to any of the infinitely many other inertial frames. In his 1905 paper Einstein refers to the ether only once:
Defenders of the ether still remained after 1905, however, since a number of physicists failed to read or understand Einstein, and those who did, came only gradually to a full appreciation of its impact on the ether. Not until about 1910 did the general opinion of physicists shift away from the ether. Among the more stubborn hold-outs were Oliver Lodge, A. A. Michelson, and Joseph John Thomson. This older group of physicists gradually died out and was replaced by a new generation that had grown up with Einstein’s theory and for which ether was an esoteric historical concept like phlogiston. References
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Ethernet: An early proprietary standard for local area networks developed by IEEE Project 802; the term has become generic for various connectors and communications techniques although the name of a standard would be more precise. [e]
Generically, Ethernet is used as a synonym for local area network. Formally, the first widely used version was version 2 of DIX Ethernet, DIX representing the companies that worked together to create it: Digital Equipment Corporation, Intel, and Xerox. DIX Ethernet was a de facto standard, but did not come from any recognized standards body, which caused problems with some organizational purchasing rules. So, a proposal was made to the what was then the Institute of Electrical and Electronic Engineers, now IEEE, to set up a formal standardization effort. This was done in February 1980, and the IEEE Project 802 is not a sequential project number, but commemorates the year and month of its formation. As it was being created, however, there were technical and commercial reasons to believe that Ethernet may not be the only way to build local area networks, so the standardization of Ethernet was put into the IEEE 802.3 subcommittee of Project 802. In the process of standardization, some improvements, generally backward compatible with DIX Ethernet, were made in the specification. The 802.3 committee, however, has remained active, building on the original Ethernet work but creating literally dozens of standards for communications systems undreamed-of by the original inventors. That which is called "Wireless Ethernet" actually comes from IEEE 802.11, with the "WiMax" variant from IEEE 802.16. DIX EthernetThe original specification specified a physical medium and means of connection to it, as well as a medium access control (i.e., a subset of data link protocol. Physical medium aspectsOriginally, the medium was a specified coaxial cable with a maximum length of 500 meters. A resistor terminator was connected at each end. This main cable was semirigid, and really could not be bent into a sufficiently flexible shape to connect directly to the computers. To allow the necessary flexibility in computer connection, there were two means of making the actual cable connection:
From the tap, for which the more modern term is medium-dependent interface (MDI), a coaxial drop cable ran to another box called a transceiver. The transceiver had two connectors, one for the coaxial drop cable, and the other a 15-pin "D-subminiature" type connected to an attachment unit interface (AUI) cable made up of twisted pairs of copper wire, not coaxial cable. The D-subminiature connector had two rows of pins arranged in a trapezoidal form, and a means of fastening it to the transceiver and to the computer's AUI interface. While the original connector called for a "slide latch" that required no tools to fasten, the slide latch was extremely unreliable in practice, and probably received almost as many foul oaths from installation engineers than it received bits from the computer. While the standard never changed, the usual fasteners were machine screws. Medium access controlContention for the medium was minimized, and resolved when it occurred, using carrier sense multiple access with collision detection (CSMA/CD) technology. In very simplified terms, the transceiver would not transmit as long as it detected a transmission in progress. If it sensed a clear line, it would transmit, but continued to monitor the line to detect if another device had simultaneously sensed a clear line and started to transmit, causing a collision. CSMA/CD then provided mechanisms for detecting the collision and breaking a tie among the devices waiting to transmit. Once bits could be transmitted, the Ethernet frame was sent, which had several fields; all lengths of which are specified in 8-bit bytes:
The Ethertype field was redefined in the medium access control part of the first IEEE 802.3 specification, becoming a length field to solve a problem in DIX, which revealed that it was unwise to send a frame with a data field shorter than 64 bytes. The length field allowed the data field in the frame to be no shorter than 64 bytes, but that the actual payload of the field could be shorter, and padded to 64 bytes. There was still a need for payload type identification, so the IEEE 802.2 Logical Link Control protocol was defined to be the first few bytes of the data field, without changing the hardware-defined header. Much later, the header was later extended, for virtual local area networks and quality of service, by the IEEE 802.1Q standard. References |
See also Aether (disambiguation).